You could just ReDim the variable again which will reset the values to zero.
Code
Sub X()
Dim V() As Double
Dim i As Long
ReDim V(10) as Double
' populate with values
For i = 1 To 10
V(i) = 99
Next i
' this is reset values to zero
ReDim V(10) as Double
For i = 1 To 10
debug.print V(i)
Next i
End Sub